'Las De La Intuición' was a single indeed in Latin America and I assume Spain a well. 'Pure Intuition' was a single in some European countries though:
In Europe, the song was translated and re-recorded in English as "Pure Intuition" and released to promote both Shakira's Oral Fixation Tour and was the official song for the campaign "Catch the Fever" by SEAT, due to the sponsorship the tour received by the automobile manufacturer. The song also received some airplay, and it managed to peak inside the top ten in Netherlands Top 40 and Top 50, as well as in Russia and Lebanon. It also charted in Romania, Slovak Republic and other Eastern Europe countries. This version was also mixed by Gustavo Celis.
I know it was a huge radio hit here in The Netherlands. The song was released to iTunes as single and peaked at #8 in the official Dutch Top 40 (sales + airplay) and #7 in the Mega Top 50 (sales only).